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yesterday
I can see when the live chat is supposed to be active but there is nothting to start a live chat !!!!!
yesterday
You sometimes have to refresh the screen as it doesn't show if the service is too busy
Also pop up blockers can cause it not to show so disable these if you use them.
Are you using this page?
https://community.talktalk.co.uk/t5/articles/our-live-chat-team/ta-p/2230529